Is there any difference between the CvCapture structure and the VideoCapture structure in OpenCV? If so, when should I use CvCapture and when to use VideoCapture?
VideoCapture is from the new C++ interface, CvCapture no longer has a public interface for use.  
When using the C++ API, VideoCapture should be used.  You should avoid mixing the two interfaces.
If you are using the C API, rather than the C++ API, several methods return a CvCapture pointer, such as cvCaptureFromFile.  
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