Here is my code:
using (DirectoryEntry AD = new DirectoryEntry("WinNT://" + Environment.MachineName +    ",computer"))
{
   DirectoryEntry NewUser = AD.Children.Add(username, "user");
   string password = username + "123";
   NewUser.Invoke("SetPassword", new object[] { password });
   NewUser.CommitChanges();
   NewUser.Close();
   DirectoryEntry grp;
   grp = AD.Children.Find(groupname, "group");
   if (grp != null)
    {
      grp.Invoke("Add", new object[] { NewUser.Path.ToString() });
    }
}
And what i want to do is to create a windows user and set the password never expired , But i do not know how to do this ?
If you're on .NET 3.5 and up, you should check out the System.DirectoryServices.AccountManagement (S.DS.AM) namespace. Read all about it here:
Basically, you can define a machine context and easily create new users on your local server:
// set up machine-level context
using (PrincipalContext ctx = new PrincipalContext(ContextType.Machine))
{
    // create new user
    UserPrincipal newUser = new UserPrincipal(ctx);
    // set some properties
    newUser.SamAccountName = "Sam";
    newUser.DisplayName = "Sam Doe";
    // define new user to be enabled and password never expires
    newUser.Enabled = true;
    newUser.PasswordNeverExpires = true;
    // save new user
    newUser.Save();
}
The new S.DS.AM makes it really easy to play around with users and groups in AD!
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