I have a 64px that I would want to scale with browser window I have added max-width 100% but the image stays the same.
Html
<img src="../images/GitHub-Mark-64px.png">
CSS
img{
    max-width: 100%;
    height: auto;
}
                If your image is smaller than the containing DIV, your CSS rule won't make it any bigger. Try to use width instead of max-width:
img{
    width: 100%;
    height: auto;
}
Addition/Edit after Comments of OP:
You can use any percentage value in this rule, like 60% (or whatever you like), but using width, not max-width (which is only a maximum limit, but not an actual size definition).
But note: It won't really look good if the original image is smaller than displayed and is "blown up".
Try using width instead of max-width in your CSS, width attribute actually sets the width of the img. However, setting it to 100% would actually cover the entire space, so perhaps you should use a lesser percentage accordingly.
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