I'm trying to understand what is the difference between them. I tried to read the documentation but it does not help alot.
HttpClientBuilder
                    .create()
                    .setMaxConnPerRoute(maxConnectionsPerRoute)
                    .setMaxConnTotal(maxConnectionTotal)
                    .build();
It's the same of setDefaultMaxPerRoute and setMaxTotal from PoolingHttpClientConnectionManager:
final PoolingHttpClientConnectionManager poolingmgr = new PoolingHttpClientConnectionManager();
poolingmgr.setDefaultMaxPerRoute(max);
poolingmgr.setMaxTotal(2 * max);
setMaxConnTotal is the total maximum connections available in the connection pool. 
setMaxConnPerRoute is the total number of connections limit to a single port or url. 
Hope it is clear now
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