I work with the scipy.optimize.minimize function.
My purpose is get w,z which minimize f(w,z)
Both w and z are n by m matrices:
[[1,1,1,1],
 [2,2,2,2]]
f(w,z) is receive parameter w and z.
I already tried the form given below:
def f(x):
   w = x[0]
   z = x[1]
   ...
minimize(f, [w,z])
but, minimize does not work well.
What is the valid form to put two matrices (n by m) into scipy.optimize.minimize?
Optimize needs a 1D vector to optimize. You are on the right track. You need to flatten your argument to minimize and then in f, start with x = np.reshape(x, (2, m, n)) then pull out w and z and you should be in business.
I've run into this issue before. For example, optimizing parts of vectors in multiple different classes at the same time. I typically wind up with a function that maps things to a 1D vector and then another function that pulls the data back out into the objects so I can evaluate the cost function. As in:
def toVector(w, z):
    assert w.shape == (2, 4)
    assert z.shape == (2, 4)
    return np.hstack([w.flatten(), z.flatten()])
def toWZ(vec):
    assert vec.shape == (2*2*4,)
    return vec[:2*4].reshape(2,4), vec[2*4:].reshape(2,4)
def doOptimization(f_of_w_z, w0, z0):
    def f(x): 
        w, z = toWZ(x)
        return f_of_w_z(w, z)
    result = minimize(f, toVec(w0, z0))
    # Different optimize functions return their
    # vector result differently. In this case it's result.x:
    result.x = toWZ(result.x) 
    return result
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