I inserted code in ItemSend and saved the ThisOutlookSession module.  It worked once and no longer works.  It was saved as VBAproject.OTM and is still there when I open the module after restarting Outlook.  
Private Sub Application_ItemSend(ByVal Item As Object, _
                                 Cancel As Boolean)
    Dim objRecip As Recipient
    Dim strMsg As String
    Dim res As Integer
    Dim strBcc As String
    On Error Resume Next
    ''# #### USER OPTIONS ####
    ''# address for Bcc -- must be SMTP address or resolvable
    ''# to a name in the address book
    strBcc = "[email protected]"
    Set objRecip = Item.Recipients.Add(strBcc)
    objRecip.Type = olBCC
    If Not objRecip.Resolve Then
        strMsg = "Could not resolve the Bcc recipient. " & _
                 "Do you want still to send the message?"
        res = MsgBox(strMsg, vbYesNo + vbDefaultButton1, _
                "Could Not Resolve Bcc Recipient")
        If res = vbNo Then
            Cancel = True
        End If
    End If
    Set objRecip = Nothing
End Sub
use and if statement on the Item's Subject field
Private Sub Application_ItemSend(ByVal Item As Object, Cancel As Boolean)
If Item.Subject = "exact match" Then
    strBcc = "[email protected]"
    Set objRecip = Item.Recipients.Add(strBcc)
    objRecip.Type = olBCC
    If Not objRecip.Resolve Then
        strMsg = "Could not resolve the Bcc recipient. " & _
                 "Do you want still to send the message?"
        res = MsgBox(strMsg, vbYesNo + vbDefaultButton1, _
                "Could Not Resolve Bcc Recipient")
        If res = vbNo Then
            Cancel = True
        End If
    End If
    Item.Save
    Set objRecip = Nothing
End If
or use if you want a contains a word in the subject
If InStr(Item.Subject, "BCCSubject") = 0 Then
End If
If you're hooking the ItemSend event, that should be in a class module with WithEvents and your code to call it in a regular module. Also, you'll want to do an Item.Save on the message for the BCC to stick.
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