atomic_compare_exchange vs mutex

Question

What is the point in replacing a mutex lock with block like this

void stack_push(stack* s, node* n)
{
    node* head;
    do
    {
        head = s->head;
        n->next = head;
    }
    while ( ! atomic_compare_exchange(s->head, head, n));
} 

Can't understand what benefit we can get by replacing mutex with this atomic excange?